From the press release:

Marvel Studios Announces THOR and CAPTAIN AMERICA: THE FIRST AVENGER Signings at Comic-Con

Marvel Studios is proud to announce the signing schedule for its two hotly-anticipated blockbuster films, Thor and Captain America: The First Avenger, at Comic-Con International in San Diego!

The complete Marvel Studios signing schedule for Saturday July 24^th at the Marvel Booth (#2329), is below:

11:15 – 12:00: Thor signing—Kenneth Branagh

12:30 – 1:30: Thor signing—Chris Hemsworth & Tom Hiddleston

2:00—3:00: Captain America: The First Avenger signing—Chris Evans & Hugo Weaving

3:30—4:30: Captain America: The First Avenger signing—Joe Johnston

Each signing is a ticketed event and requires a specific ticket for that individual signing. Fans should come to the Marvel Booth (#2329) as soon the convention opens to the public on Saturday morning for a chance (no purchase necessary) to receive one of the limited number of signing tickets.

Don’t miss your chance to experience a once-in-a-lifetime event at Comic-Con International in San Diego, courtesy of Marvel Studios on Saturday, July 24^th, at the Marvel Booth (#2329)!

THOR will come to theatres on May 6, 2021 and CAPTAIN AMERICA: THE FIRST AVENGER will be released on July 22, 2011.  Paramount Pictures will distribute both films.

Please Note That All Times & Guests Are Subject To Change.

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3. Chris Evans Rumoured to Accept the Role of Captain America
4. Filming on The First Avenger: Captain America Movie set for a June 2010 Start
5. Marvel Releases an Avengers #1 Teaser Image, Featuring Captain America